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Quenching and tempering

When steel is rapidly cooled (quenched) from austenite, martensite forms — a hard and brittle structure because the carbon gets trapped in the lattice. Afterwards the steel is tempered by moderate heating, which makes it less brittle with slightly lower hardness, giving a better compromise between toughness and hardness.

austenite→quenchmartensite→tempertougher steel\text{austenite} \xrightarrow{\text{quench}} \text{martensite} \xrightarrow{\text{temper}} \text{tougher steel}quenching and tempering in two steps

Example

A hand tool is quenched and tempered to balance hardness (wear resistance) against toughness (resistance to brittle fracture).

Quenched but untempered steel is often too brittle for practical use — tempering is rarely optional.
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Part of Materials Technology: Heat treatment and corrosion.